Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]
Synthesis and behavior in solution of the triple cubane- and windmill-type framework isomers of an organorhodium tungsten oxide cluster [(Cp*Rh)4W4O16]
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DOI：
10.1002/aoc.447
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发表时间：
2003-06-01
影响因子：
3.9
通讯作者：
Isobe, K
中科院分区：
文献类型：
--
作者：
Nishikawa, K;Kido, K;Isobe, K
在不同的反应温度下，从[Cp * Rh]（2+）和[WO 4]（2-）的乙腈体系中选择性地分离出了[（Cp*Rh）（4）W 4 O 16]氧化物簇合物的两种几何异构体：三立方烷型和风车型.这两种异构体在某些溶液中相互转化，其特征在于X射线衍射。版权所有（C）2003约翰威利父子有限公司。
Two geometrical isomers of a [(Cp*Rh)(4)W4O16] oxide cluster, a triple cubane-type and a windmill-type, are isolated selectively from the systems of [Cp*Rh](2+) and [WO4](2-) in CH3CN using different reaction temperatures. Both isomers, which interconvert in certain solutions, are characterized by X-ray diffraction. Copyright (C) 2003 John Wiley Sons, Ltd.