Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition.
Formation of nickeladihydropyran by oxidative addition of cyclopropyl ketone. Key intermediate in nickel-catalyzed cycloaddition.
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DOI：
10.1021/ja060220y
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发表时间：
2006-03
影响因子：
15
通讯作者：
S. Ogoshi;Midue Nagata;H. Kurosawa
中科院分区：
文献类型：
--
作者：
S. Ogoshi;Midue Nagata;H. Kurosawa
环丙基苯基酮与Ni（cod）2和PCy3生成的Ni（PCy3）发生氧化加成反应，生成二氢吡喃镍，该化合物是Ni（0）催化的均环或杂环加成反应的关键中间体。
Cyclopropyl phenyl ketone underwent oxidative addition to Ni(PCy3) generated from Ni(cod)2 and PCy3 to give a nickeladihydropyran, which is a key intermediate for the Ni(0)-catalyzed homo- or heterocycloaddition to give cyclopentane compounds having two carbonyl substituents at the 1,3-position.