Enantiotopically selective oxidation of .alpha.,.omega.-diols with enzyme systems of microorganisms
Enantiotopically selective oxidation of .alpha.,.omega.-diols with enzyme systems of microorganisms
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DOI：
10.1021/jo00133a033
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发表时间：
1982-06
影响因子：
3.6
通讯作者：
H. Ohta;Hatsuki Tetsukawa;N. Noto
中科院分区：
文献类型：
--
作者：
H. Ohta;Hatsuki Tetsukawa;N. Noto
结果葡萄糖酸杆菌和醋酸杆菌是已知的氧化多种伯醇和仲醇的细菌。7因此，通过使用2-甲基丙烷-1，3-二醇（Ia）作为具有带有前手性中心的α-二醇官能团的最简单底物，检测了各种葡萄糖酸菌菌株。用葡糖酸杆菌氧化<$-取代的丙烷-1，3-二醇1。在16株葡萄糖酸杆菌中，
Results Gluconobacter and Acetobacter havebeen well-known to oxidize a variety of primary and secondary alcohols. 7 Thus, various strains of Gluconobacter were examined by using 2-methylpropane-1, 3-diol (la) as the simplest sub-strate that has,-diol functions with a prochiral center. Oxidation of¿-Substituted Propane-1, 3-diols 1 with Gluconobacters. Among 16 strains of Gluconobacter and