Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, ß-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21]
Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, ß-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21]
复制标题
溶剂热氟化铟化学：K5In3F14、-(NH4)3InF6 和 [NH4]3[C6H21N4]2[In4F21] 的合成和晶体结构
DOI：
10.1016/j.jssc.2009.11.022
复制
发表时间：
2010
影响因子：
3.3
通讯作者：
Jayasundera A
中科院分区：
文献类型：
--
作者：
Jayasundera A
介绍了三种氟化铟的溶剂热合成方法和晶体结构。{sub3}F{sub14}(1)中的K{sub5}和β-(NH{sub4}){sub3}InF{sub6}(2)分别是已知的无机结构类型白垩石和冰晶石的变体，后者表现出复杂而明显的结构扭曲。[NH{sub4}]{sub3}[C{sub6}H{sub21}N{sub4}]{sub2}[在{sub4}F{sub21}](3)表示一种新的杂化组合物，显示独特的三聚金属氟化物建筑单元。-图形摘要：溶剂热合成已被用来制备三种氟化铟，包括一种新型的杂化材料，该材料含有以trn为模板的独特的[In{sub3}F{sub15}]三聚体。
The solvothermal syntheses and crystal structures of three indium fluorides are presented. K{sub 5}In{sub 3}F{sub 14} (1) and beta-(NH{sub 4}){sub 3}InF{sub 6} (2) are variants on known inorganic structure types chiolite and cryolite, respectively, with the latter exhibiting a complex and apparently novel structural distortion. [NH{sub 4}]{sub 3}[C{sub 6}H{sub 21}N{sub 4}]{sub 2}[In{sub 4}F{sub 21}] (3) represents a new hybrid composition displaying a unique trimeric metal fluoride building unit. - Graphical abstract: Solvothermal synthesis has been used to prepare three indium fluorides, including a novel hybrid material containing a unique [In{sub 3}F{sub 15}] trimer templated by tren.