Occurrence of Pesticides in Rain of the Axios River Basin, Greece
Occurrence of Pesticides in Rain of the Axios River Basin, Greece
复制标题
希腊阿克西奥斯河流域雨中农药的出现
DOI：
--
复制
发表时间：
1999
期刊：
影响因子：
--
通讯作者：
E. Papadopoulou
中科院分区：
文献类型：
--
作者：
Emmanouil Charizopoulos;E. Papadopoulou
Axios河流域是希腊最发达的农业区之一。在1997 - 1998年期间，从8个采样站收集了总共205次降雨事件的样本，对其中186次事件（90%）的农药残留物进行了分析，至少有一次检测呈阳性。在160种目标农药和一些主要的转化产物中，通过固相萃取（SPE）回收并通过GC-ITMS分析，至少在一次降雨事件中发现了47种化合物。最常见的农药包括甲草胺（49%）、林丹（44%）、甲基对硫磷（38%）、莠去津（30%）、五氯硝基苯（28%）、异丙甲草胺（24%）、扑草净（23%）和灭草酯（22%）。二嗪农、毒死蜱、杀扑磷、乙氧氟草胺和敌百虫磷的含量占分析样品的14 - 17%。剩余的目标分析物存在于少于10%的分析样品中。单个化合物的浓度范围为0.002 - 6.82 μg/L。在施用季节，农药浓度较高。那个...
The Axios River Basin is one of the most developed agricultural areas of Greece. Samples from a total of 205 rain events collected from eight sampling stations during 1997−1998 were analyzed for pesticide residues of which 186 events (90%) yielded at least one positive detection. Among 160 target pesticides and some major conversion products recovered by solid-phase extraction (SPE) and analyzed by GC−ITMS, 47 compounds were found in at least one rain event. The most frequently found pesticides included alachlor (49%), lindane (44%), parathion-methyl (38%), atrazine (30%), quintozene (28%), metolachlor (24%), prometryne (23%), and molinate (22%). Occurrences of diazinon, chlorpyrifos-ethyl, methidathion, ethofumesate, and parathion accounted for 14−17% of the samples analyzed. The remaining target analytes were present in less than the 10% of the analyzed samples. Concentrations of individual compound ranged from 0.002 to 6.82 μg/L. Greater pesticide concentrations occurred during application seasons. The...