Systematic Study of Pnictogen-Fused Heterofluorenes

Systematic Study of Pnictogen-Fused Heterofluorenes
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磷元素稠合杂芴的系统研究

DOI:
10.1021/acs.inorgchem.2c00158
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发表时间:
2022
影响因子:
4.6
通讯作者:
Naka Kensuke
Naka Kensuke
中科院分区:
化学2区
文献类型:
--
作者:
Inaba Ryoto;Oka Kouki;Iwami Takahiro;Miyake Yusuke;Tajima Kunihiko;Imoto Hiroaki;Naka Kensuke

文献摘要

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杂原子熔合的π共轭分子引起了人们的极大关注,并对这种融合的各种元素进行了研究。在本论文中,我们重点研究了尼可托根熔合杂荧烯。系统地研究了它们的结构、与O2和I2的反应活性、与Au的配位能力以及光物理性质,以更好地理解π原子对分子性质的影响。
Heteroatom-fused π-conjugated molecules have attracted considerable attention, and various elements for such fusion have been investigated. Herein, we focused on pnictogen-fused heterofluorenes. The structures, reactivity with O2and I2, coordination ability to AuCl, and photophysical properties were systematically studied to better understand the effects of pnictogen atoms on the nature of π-conjugated molecules.