Borohydride anions as terminal ligands on a Fe/Mo/S cluster. Synthesis, structure, and characterization of the [(Cl4-cat)(PPr3)MoFe3S4(BH4)2]2(Bu4N)4 double-fused cubane.
Borohydride anions as terminal ligands on a Fe/Mo/S cluster. Synthesis, structure, and characterization of the [(Cl4-cat)(PPr3)MoFe3S4(BH4)2]2(Bu4N)4 double-fused cubane.
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DOI：
10.1021/ic049275w
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发表时间：
2004-09
影响因子：
4.6
通讯作者：
M. Koutmos;D. Coucouvanis
中科院分区：
文献类型：
--
作者：
M. Koutmos;D. Coucouvanis
The synthesis and structure of the first Mo/Fe/S/BH(4) cluster is reported. Reaction of (Cl(4)-cat)(2)Mo(2)Fe(6)S(8)(PPr(3))(6) with 4 equiv of Bu(4)NBH(4) results in the formation of [(Cl(4)-cat)(PPr(3))MoFe(3)S(4)(BH(4))(2)](2)(Bu(4)N)(4) (Cl(4)-cat = tetrachloro-catecholate) which has been fully characterized. X-ray structural determination of this double-fused cubane reveals four BH(4)(-) ligands bound to four Fe atoms in a bidentate fashion. A synopsis of the solution characterization as well as the reactivity of this cluster is also presented.
