4-(4-pyridyl)benzoic acid (pybenH) dimer : An efficient and reasonable design for a long linear bidentate building block employed in metal-organic coordination framework

4-(4-pyridyl)benzoic acid (pybenH) dimer : An efficient and reasonable design for a long linear bidentate building block employed in metal-organic coordination framework
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DOI:
10.1246/cl.2006.614
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发表时间:
2006-05
期刊:
影响因子:
1.6
通讯作者:
R. Sekiya;S. Nishikiori;K. Ogura
R. Sekiya;S. Nishikiori;K. Ogura
中科院分区:
化学4区
文献类型:
--
作者:
R. Sekiya;S. Nishikiori;K. Ogura

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4-(4-吡啶基)苯甲酸(pybenH)、Ni 2+、SCN -和芳香客体(萘或二苯并[a,h]蒽)自组装得到两种同构包合化合物,其中pybenH配体形成相应的二聚体,作为双齿结构的构建单元,长度约为20.86 a。
Self-assembly of 4-(4-pyridyl)benzoic acid (pybenH), Ni 2+ , SCN - and an aromatic guest (naphthalene or dibenz[a,h]anthracene) gave two isostructural inclusion compounds, in which pybenH ligands form the corresponding dimers acting as bidentate building blocks with a length of ca. 20.86 A.