Reversible transformation between ionic liquids and coordination polymers by application of light and heat
Reversible transformation between ionic liquids and coordination polymers by application of light and heat
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DOI：
10.1039/c6cc02807a
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发表时间：
2016-01-01
影响因子：
4.9
通讯作者：
Mochida, Tomoyuki
中科院分区：
文献类型：
--
作者：
Funasako, Yusuke;Mori, Shotaro;Mochida, Tomoyuki
通过光和热的作用，实现了离子液体和配位聚合物之间的可逆转变。紫外光照射将透明液体转变为黄色固体；由于加热，会发生相反的反应。这种转变伴随着Ru络合物分子内和分子间配位键的剧烈切换。这是一种新的材料转化方法，连接了离子液体和配位聚合物领域。
Reversible transformation between an ionic liquid and a coordination polymer by application of light and heat has been achieved. Ultraviolet light irradiation transforms the transparent liquid to a yellow solid; a reverse reaction occurs due to the application of heat. The transformation accompanies drastic switching of intra- and inter-molecular coordination bonds of a ruthenium complex. This is a novel material conversion methodology that connects the fields of ionic liquids and coordination polymers.