(6S)-Hydroxy-3-oxo-α-ionol glucosides from Capparis spinosa fruits
(6S)-Hydroxy-3-oxo-α-ionol glucosides from Capparis spinosa fruits
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DOI：
10.1016/s0031-9422(01)00399-5
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发表时间：
2002-02-01
期刊：
影响因子：
3.8
通讯作者：
Rüedi, P
中科院分区：
文献类型：
--
作者：
Çalis, I;Kuruüzüm-Uz, A;Rüedi, P
从刺山柑成熟果实中分得两个新的（6S）-羟基-3-氧代-α-紫罗兰醇糖苷，以及一个异戊烯基糖苷和一个corchoionoside C（（6S，9 S）-rososide）。其结构是根据光谱、手性和化学证据确定的。此外，C-9的C-13-共振被发现在分配紫罗兰醇糖苷中该中心的绝对构型时具有特别的诊断价值。α-紫罗兰醇衍生物是（+）-（S）-脱落酸的代谢物。(C)2002爱思唯尔科技有限公司版权所有。
Two new (6S)-hydroxy-3-oxo-alpha-ionol glucosides, together with corchoionoside C ((6S,9S)-roseoside) and a prenyl glucoside, were isolated from mature fruits of Capparis spinosa. The structures were established on the basis of spectroscopic, chiroptic and chemical evidence. In addition, the C-13-resonance of C-9 was found to be of particular diagnostic value in assigning the absolute configuration at that center in ionol glycosides. The alpha-ionol derivatives are metabolites of (+)-(S)-abscisic acid. (C) 2002 Elsevier Science Ltd. All rights reserved.