Dependence of the Mixed-Valence States on Crystal Form in 1′,1″′-Ditetradecylbiferrocenium Triiodide
Dependence of the Mixed-Valence States on Crystal Form in 1′,1″′-Ditetradecylbiferrocenium Triiodide
复制标题
1′,1″′-双十四烷基二茂铁三碘化物混合价态对晶型的依赖性
DOI：
10.1246/cl.1989.1075
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发表时间：
1989
影响因子：
1.6
通讯作者：
H. Sano
中科院分区：
文献类型：
--
作者：
S. Nakashima;H. Sano
在 1',1"'-二十四烷基二茂铁三碘化物中观察到混合价态对晶型的显着依赖性。一种晶体形式显示出与温度无关的俘获价态，而另一种晶体形式被发现是温度依赖性价态，其中观察到在较低温度下的俘获价态和在较高温度下的平均价态。
Remarkable dependence of the mixed-valence states on crystal form was observed in 1′,1″′-ditetradecylbiferrocenium triiodide. One crystal form showed a temperature-independent trapped-valence state, while the other was found to be a temperature-dependent valence state in which a trapped-valence state at lower temperatures and an averaged-valence state at higher temperatures are observed.