A General Method for the Chromatographic Separation of Nonionic Surface-Active Agents and Related Materials.
A General Method for the Chromatographic Separation of Nonionic Surface-Active Agents and Related Materials.
复制标题
非离子表面活性剂及相关材料的色谱分离的通用方法。
DOI：
10.1021/ac60206a028
复制
发表时间：
1963
影响因子：
7.4
通讯作者：
M. J. Rosen
中科院分区：
文献类型：
--
作者：
M. J. Rosen
以硅胶为吸附剂，建立了非离子表面活性物质相互分离及相关非离子物质分离的通用层析方法。吸附在硅胶柱上的混合物，用氯仿，1：99(v/v)依次洗脱分离。乙醚-氯仿，1：1(v/v)乙醚-氯仿，1：1(v/v)丙酮-氯仿，1：19(v/v)甲醇-氯仿，1：9(v/v)甲醇-氯仿和1×2(v/v)甲醇-氯仿。本文介绍了几种三组分和四组分混合物的实验结果。含非离子表面活性剂的混合物通常含有一种以上的非离子物质。这些组合物通常同时含有水溶和油溶表面活性剂，以获得更好的性能平衡，此外，通常还含有其他非离子、非表面活性物质，如碳氢化合物
A general chromatographic method has been developed for separating nonionic surface-active agents from each other and fromrelated nonionic materials, using silica gel as adsorbent. The mixture, adsorbed on a silica gel column, is separated by eluting suc-cessively with chloroform, 1: 99 (v./v.) ethyl ether-chloroform, 1: 1 (v./v.) ethyl ether-chloroform, 1: 1(v./v.) acetone-chloroform, 1: 19(v./v.) methanol-chloroform, 1: 9(v./v.) methanol-chloroform, and 1¡ 2 (v./v.) methanol-chloroform. Results obtained with a number of three-and four-component mixtures are de-scribed.COMPOSITIONS CONTAINING nonionic surface-active agents commonly contain more than one nonionic substance. These compositions often con-tain both water-soluble and oil-soluble surfactants to obtain a better balance of properties, and in addition, usually contain other nonionic, nonsurface-active materials, such as hydrocarbon