HEMILABILE P,O-LIGANDS IN PALLADIUM-CATALYZED C-C LINKAGES - CODIMERIZATION OF ETHYLENE AND STYRENE AND COOLIGOMERIZATION OF ETHYLENE AND CARBON-MONOXIDE
HEMILABILE P,O-LIGANDS IN PALLADIUM-CATALYZED C-C LINKAGES - CODIMERIZATION OF ETHYLENE AND STYRENE AND COOLIGOMERIZATION OF ETHYLENE AND CARBON-MONOXIDE
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DOI：
10.1039/c39930001632
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发表时间：
1993-11-07
影响因子：
--
通讯作者：
WAGNER, T
中科院分区：
文献类型：
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作者：
BRITOVSEK, GJP;KEIM, W;WAGNER, T
合成了中性和阳离子钯烯丙基双齿配合物Ph_2P（CH_2）_nCO_2 ~-（n = 1-3;配合物n = 1和2）或Ph_2P（CH_2）_nCO_2R（n = 1-3; R = Me，Et），并将其用作乙烯和苯乙烯共聚合及乙烯和一氧化碳共低聚的催化剂。
Neutral and cationic palladium allyl complexes with bidentate ligands Ph2P(CH2)nCO2- (n = 1-3; X-ray crystal structure determination for complexes with n = 1 and 2) or Ph2P(CH2)nCO2R(n = 1-3; R = Me, Et) have been prepared and used as catalysts for the codimerization of ethylene and styrene and for the cooligomerization of ethylene and carbon monoxide.