Long Stokes shifts and vibronic couplings in perfluorinated polyanilines

Long Stokes shifts and vibronic couplings in perfluorinated polyanilines
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DOI:
10.1039/c7cc00471k
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发表时间:
2017-02-28
影响因子:
4.9
通讯作者:
Porfyrakis, Kyriakos
Porfyrakis, Kyriakos
中科院分区:
化学2区
文献类型:
--
作者:
Dallas, Panagiotis;Rasovic, Ilija;Porfyrakis, Kyriakos

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报道了表面活性剂的加入对液-液界面法合成的全氟化聚苯胺光学性质的影响。在Triton X-100存在下,我们得到了氢氟醚-水体系中低聚物的很长的斯托克斯位移,205 nm,以及甲苯-水体系的振动精细特征。
We report the effect of surfactant addition on the optical properties of perfluorinated polyanilines synthesized through liquid-liquid interfaces. We obtained very long Stokes shifts, 205 nm, for oligomers derived from a hydrofluoroether-water system in the presence of Triton X-100 as a surfactant, and vibronic fine features from a toluene-water system.