NOVEL REAGENT SYSTEM FOR CONVERTING A HYDROXY-GROUP INTO AN IODO-GROUP IN CARBOHYDRATES WITH INVERSION OF CONFIGURATION
NOVEL REAGENT SYSTEM FOR CONVERTING A HYDROXY-GROUP INTO AN IODO-GROUP IN CARBOHYDRATES WITH INVERSION OF CONFIGURATION
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DOI：
10.1039/c39790000978
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发表时间：
1979-01-01
影响因子：
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通讯作者：
SAMUELSSON, B
中科院分区：
文献类型：
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作者：
GAREGG, PJ;SAMUELSSON, B
描述了在升高的温度下在甲苯中使用三苯基膦、碘和咪唑或三苯基膦和2，4，5-三碘咪唑将碳水化合物中的伯羟基和仲羟基转化为碘基的有效转化。
Efficient conversions of primary and secondary hydroxy-groups into iodo-groups, with inversion, in carbohydrates are described using either triphenylphosphine, iodine, and imidazole or triphenylphosphine and 2,4,5-tri-iodoimidazole in toluene at elevated temperature.