BINUCLEAR BIS(MU-OXO)DIMANGANESE(III,IV) AND BIS(MU-OXO)DIMANGANESE(IV,IV) COMPLEXES WITH N,N'-BIS(2-PYRIDYLMETHYL)-1,2-ETHANEDIAMINE
BINUCLEAR BIS(MU-OXO)DIMANGANESE(III,IV) AND BIS(MU-OXO)DIMANGANESE(IV,IV) COMPLEXES WITH N,N'-BIS(2-PYRIDYLMETHYL)-1,2-ETHANEDIAMINE
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DOI：
10.1021/ic00328a034
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发表时间：
1990-02-07
影响因子：
4.6
通讯作者：
PEDERSEN, E
中科院分区：
文献类型：
--
作者：
GOODSON, PA;GLERUP, J;PEDERSEN, E
结论现有的实验证据支持中心对称双核金属羰基配合物的溶剂化显色主要是由偶极-偶极相互作用引起的观点。然而，单核和双核物种溶剂化显色差异的原因仍不清楚。显然，在正确理解这些物质溶剂化变色现象的微妙之处之前，需要进行更详细的研究，使用更多的溶剂和相关系列的桥连配体。致谢。我们感谢海军研究办公室（华盛顿特区）对这项工作的支持。
Conclusion The available experimental evidence supports the view that the solvatochromism of centrosymmetric dinuclearmetal carbonyl complexes is caused mainly by dipole-dipole interactions. How-ever, the reasons for differences inthe solvatochromism of the mono-and dinuclear species remain unclear. Clearly, more de-tailed studies, employing larger numbers of solvents and related series of bridging ligands, are necessary before the subtleties of the solvatochromism of these species can be properly understood.Acknowledgment. We are grateful tothe Office of Naval Research (Washington, DC) for support of this work.