Selenium borohydride reaction as a versatile platform for the straightforward preparation of selenide-containing topological polymers
Selenium borohydride reaction as a versatile platform for the straightforward preparation of selenide-containing topological polymers
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硼氢化硒反应作为直接制备含硒拓扑聚合物的通用平台
DOI：
10.1039/c7py00676d
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发表时间：
2017-07
影响因子：
4.6
通讯作者：
Xiulin Zhu
中科院分区：
文献类型：
--
作者：
Chunlai Ding;Caiwei Fan;Xiangqiang Pan;Zhengbiao Zhang;Jian Zhu;Xiulin Zhu
基于硒化物功能化交换树脂与末端功能化聚合物的反应，建立了一种制备具有所需拓扑结构的含硒化物聚合物的方法，该方法具有结构可行性广、条件温和、效率高、可回收性好等优点。通过可逆失活自由基聚合（例如原子转移自由基聚合和可逆加成断裂链转移聚合）制备的聚合物可以用作前体，从而能够生产具有多种定制结构的聚合物。不同类型的聚合物前驱体，如聚（苯乙烯）、聚（丙烯酸酯）、聚（乙酸乙烯酯）和聚（N-乙烯基-2-吡咯烷酮）被成功地用于有效制备结构明确的含硒聚合物，验证了当前方法的多功能性。此外，具有复杂拓扑结构（例如环状和稠环）的含硒聚合物也可以使用具有特定结构的聚合物前体（例如单、二或四手爪聚合物）方便地制备。
A method for preparing selenide-containing polymers with desired topologies is established based on the reaction of a selenide-functionalized exchange resin with end-functionalized polymers that shows advantages such as wide structural feasibility, mild conditions, high efficiency and good recyclability. Polymers prepared through reversible-deactivation radical polymerization, e.g., atom-transfer radical polymerization and reversible addition–fragmentation chain transfer polymerization, could be used as precursors, enabling the production of polymers with diverse tailor-made architectures. Different types of polymer precursors, such as poly(styrene), poly(acrylate), poly(vinyl acetate) and poly(N-vinyl-2-pyrrolidone) were successfully used to efficiently prepare well-defined selenide-containing polymers, which verified the versatility of the current method. Furthermore, selenide-containing polymers with complex topologies, such as cyclic and fused-cyclic, were also conveniently fabricated using polymer precursors with specific architectures, such as mono-, di- or tetratelechelic polymers.
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影响因子：
15
作者：
Takuya Yamamoto;Sakyo Yagyu;Y. Tezuka
通讯作者：
Takuya Yamamoto;Sakyo Yagyu;Y. Tezuka
影响因子：
4.6
作者：
Jindong Zeng;Jian Zhu;Xiangqiang Pan;Zhengbiao Zhang;Nianchen Zhou;Zhenping Cheng;Wei Zhang-;Xiu-lin Zhu-Xiu
通讯作者：
Jindong Zeng;Jian Zhu;Xiangqiang Pan;Zhengbiao Zhang;Nianchen Zhou;Zhenping Cheng;Wei Zhang-;Xiu-lin Zhu-Xiu
影响因子：
8.6
作者：
Dana B. Sulas;Kai Yao;Jeremy J. Intemann;Spencer T. Williams;Chang‐Zhi Li;Chu‐Chen Chueh;J. J. Richards-J.;Yuyin Xi;L. Pozzo;Cody W. Schlenker;A. Jen;D. Ginger
通讯作者：
Dana B. Sulas;Kai Yao;Jeremy J. Intemann;Spencer T. Williams;Chang‐Zhi Li;Chu‐Chen Chueh;J. J. Richards-J.;Yuyin Xi;L. Pozzo;Cody W. Schlenker;A. Jen;D. Ginger
影响因子：
5.5
作者：
Ladaviere, Catherine;Lacroix-Desmazes, Patrick;Delolme, Frederic
通讯作者：
Delolme, Frederic
DOI：
10.1007/bf00488505
发表时间：
1977
期刊：
Fresenius' Zeitschrift für analytische Chemie
影响因子：
--
作者：
L. Futekov;R. Paritschkova;H. Specker
通讯作者：
L. Futekov;R. Paritschkova;H. Specker