Regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals.
Regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals.
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简单烯烃与三溴化铟和烯酮甲硅烷基缩醛的区域选择性碳化。
DOI：
10.1021/ol1012108
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发表时间：
2010
期刊：
影响因子：
5.2
通讯作者：
A. Baba
中科院分区：
文献类型：
--
作者：
Yoshihiro Nishimoto;H. Ueda;Y. Inamoto;M. Yasuda;A. Baba
用三溴化铟和乙烯酮硅缩醛实现了简单烯烃的区域选择性碳茚化反应。各种烯烃如乙烯、1-烯烃和环烯烃可用于该反应体系。环己烯碳茚化反应生成的烷基铟产物表现出反加成机理。
The regioselective carboindation of simple alkenes with indium tribromide and ketene silyl acetals was accomplished. Various alkenes such as ethylene, 1-alkenes, and cyclic alkenes were applicable for this reaction system. The alkylindium product from the carboindation of cyclohexene revealed an anti addition mechanism.