Pyridine N-Oxide-Promoted Cobalt-Catalyzed Dioxygen-Mediated Methane Oxidation.
Pyridine N-Oxide-Promoted Cobalt-Catalyzed Dioxygen-Mediated Methane Oxidation.
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DOI：
10.1021/acs.joc.3c00770
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发表时间：
2023-07
期刊：
影响因子：
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通讯作者：
Bingyin Meng;L. Liu;Xiao-Qiu Shen;Wu Fan;Suhua Li
中科院分区：
文献类型：
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作者：
Bingyin Meng;L. Liu;Xiao-Qiu Shen;Wu Fan;Suhua Li
The partial oxidation of methane with O2 is significant due to its potential of providing abundant chemical feedstock. Only a few examples realized this type of reaction in homogeneous solvent systems, most of which are in low efficiency. Herein, we present a pyridine N-oxide-promoted cobalt-catalyzed O2-mediated methane oxidation to produce methylene bis(trifluoroacetate) with productivity over 500 molester molmetal-1 h-1.
