End-Functionalized Polymers of Styrene and p-Methylstyrene by Living Cationic Polymerization with Functionalized Initiators
End-Functionalized Polymers of Styrene and p-Methylstyrene by Living Cationic Polymerization with Functionalized Initiators
复制标题
通过官能化引发剂的活性阳离子聚合得到苯乙烯和对甲基苯乙烯的末端官能化聚合物
DOI：
10.1021/ma00083a005
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发表时间：
1994
期刊：
影响因子：
5.5
通讯作者：
T. Higashimura
中科院分区：
文献类型：
--
作者：
Kazuaki Miyashita;M. Kamigaito;M. Sawamoto;T. Higashimura
以乙烯基醚的HCl加成物[2; CH 3CH（OCH 2 -CH 2X）Cl; X=氯离子、苯甲酸根、乙酸根、邻苯二甲酰亚胺、甲基丙烯酸根]为引发剂，在-15 ° C下进行活性阳离子聚合，合成了一系列苯乙烯和对甲基苯乙烯的α-末端官能化聚合物.当在nBu 4 NCl存在下与SnCl 4（活化剂）偶联时，这些官能化引发剂（2）定量引发活性聚合，其中2的碳-氯键被SnCl 4活化
A series of α-end-functionalized polymers of styrene and p-methylatyrene were synthesized by living cationic polymerizations in CH 2 Cl 2 at -15°C initiated with the HCl adducts [2; CH 3 CH(OCH 2 -CH 2 X)Cl; X=chloride, benzoate, acetate, phthalimide, methacrylate] of vinyl ethera carrying pendant substituents X that serve as the terminal functionalities in the products. When coupled with SnCl 4 (activator) in the presence of nBu 4 NCl, these functionalized initiators (2) quantitatively initiated living polymerizations where the carbon-chlorine bond of 2 was activated by SnCl 4