Fragmentation and intracluster reactions of hydrated aluminum cations Al+(H2O)(n), n=3-50
Fragmentation and intracluster reactions of hydrated aluminum cations Al+(H2O)(n), n=3-50
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DOI：
10.1021/ja9606438
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发表时间：
1996-08-07
影响因子：
15
通讯作者：
Bondybey, VE
中科院分区：
文献类型：
--
作者：
Beyer, M;Berg, C;Bondybey, VE
在无碰撞环境中，研究了水合铝团簇阳离子Al ~+（HO_2）（n）（n=3-50）在室温红外背景“黑体”诱导下的单分子碎裂.一个有趣的尺寸依赖性的簇内反应，导致铝阳离子的氧化和消除分子氢被观察到。结果进行了讨论，并与最近类似的研究水合镁团簇。
Hydrated aluminum cluster cations Al+(HO2)(n) with n=3-50 were stored in a collision-free environment, and their unimolecular fragmentation induced by the room temperature ''black body'' infrared background was studied. An interesting size-dependent intracluster reaction resulting in oxidation of the aluminum cation and elimination of molecular hydrogen was observed. The results are discussed and compared with similar recent studies of hydrated magnesium clusters.