An alternative route towards low-cost Cu2ZnSnS4 thin film solar cells
An alternative route towards low-cost Cu2ZnSnS4 thin film solar cells
复制标题
低成本 Cu2ZnSnS4 薄膜太阳能电池的替代途径
DOI：
10.1016/j.surfcoat.2013.04.052
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发表时间：
2013-10-01
影响因子：
5.4
通讯作者：
Liu, Yexiang
中科院分区：
文献类型：
--
作者：
Tang, Ding;Wang, Qinglong;Liu, Yexiang
提出了一种非真空、低成本制备薄膜太阳电池吸收层Cu2ZnSnS4(CZTS)薄膜的方法。该工艺包括铜锌锡复合氧化物纳米颗粒的合成、复合氧化物墨水的制备、复合氧化物薄膜的沉积和随后的硫化处理。通过控制化学共沉淀条件，可以得到成分和粒径合适的铜锌锡复合氧化物纳米粒子。研究了硫化温度对CS薄膜的成分、结构、形貌、光学和电学性能的影响。X射线衍射、拉曼光谱和X射线光电子能谱分析证实了硫化后生成了CZTS相。所制备的CZTS薄膜具有多孔结构，光学带隙约为135 eV。用550℃硫化处理的CZTS薄膜制成的太阳能电池的转换效率为1.22%。(C)2013年提交人。爱思唯尔出版，版权所有。
A non-vacuum and low-cost route to fabrication of Cu2ZnSnS4 (CZTS) thin film as absorber layer for thin film solar cell is demonstrated. The process involves synthesis of Cu-Zn-Sn composite oxide nanoparticles, preparation of composite oxide ink, deposition of composite oxide thin film and subsequent sulfurization treatment. Cu-Zn-Sn composite oxide nanoparticles with proper composition and particle size can be obtained by controlling the chemical co-precipitation conditions. The effects of sulfurization temperature on the compositional, structural, morphological, optical and electrical properties of the CS thin films were investigated. XRD, Raman and X-ray photoelectron spectroscopy analyses confirmed the formation of CZTS phase after sulfurization. The prepared CZTS thin films exhibit porous morphology and an optical band gap about 135 eV. The solar cells fabricated with the CZTS thin film sulfurized at 550 degrees C showed a conversion efficiency of 1.22%. (C) 2013 The Authors. Published by Elsevier B.V. All rights reserved.