Protonation activates anion binding and alters binding selectivity in new inherently fluorescent 2,6-bis(2-anilinoethynyl)pyridine bisureas

Protonation activates anion binding and alters binding selectivity in new inherently fluorescent 2,6-bis(2-anilinoethynyl)pyridine bisureas
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DOI:
10.1039/b901643k
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发表时间:
2009-01-01
影响因子:
4.9
通讯作者:
Johnson, Darren W.
Johnson, Darren W.
中科院分区:
化学2区
文献类型:
--
作者:
Carroll, Calden N.;Berryman, Orion B.;Johnson, Darren W.

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一类新的2,6-双(2-苯胺乙基)吡啶类双脲类化合物与卤化物形成1:1配合物;质子化提高了一个数量级以上的结合,改变了结合的选择性,并提供了阴离子结合的比色指示。
A new class of 2,6-bis(2-anilinoethynyl)pyridine-based bisureas forms 1:1 complexes with halides; protonation enhances binding by over one order of magnitude, alters the binding selectivity, and provides a colorimetric indication of anion binding.