Multitechnique elemental depth profiling of InAlGaN and InAlN films

Multitechnique elemental depth profiling of InAlGaN and InAlN films
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InAlGaN 和 InAlN 薄膜的多技术元素深度分析

DOI:
10.1116/1.5019635
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发表时间:
2018
期刊:
Journal of Vacuum Science & Technology. B. Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena
影响因子:
--
通讯作者:
S. Legendre
S. Legendre
中科院分区:
--
文献类型:
--
作者:
Y. Mazel;E. Nolot;J. Barnes;M. Charles;R. Bouveyron;M. Mrad;A. Tempez;S. Legendre

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这项工作显示了等离子体谱分析飞行时间质谱(PP-TOFMS)用于测定用于高电子迁移率晶体管的InAlGaN薄膜中的元素组成和分布的能力。将PP-TOFMS结果与波长色散x射线荧光分析的元素组成测定和x射线光电子能谱和飞行时间二次离子质谱(TOF-SIMS)的元素分布测定进行了比较。建立了相对灵敏度因子,用于PP-TOFMS和TOF-SIMS结果的比较。在无需校准的情况下,PP-TOFMS能够测定薄膜中In和Al的相对组成,精度为10 rel. %。从PP-TOFMS技术获得的深度剖面在几分钟内获得,并且显示出与TOF-SIMS测量非常相似的In, Al和Ga分布,因此PP-TOFMS已被证明是对TOF-SIMS分析的有价值的补充,用于快速工艺开发。
This work shows the capabilities of the plasma profiling time of flight mass spectrometry (PP-TOFMS) for the determination of elemental composition and distribution in InAlGaN thin films used for high electron mobility transistors. The PP-TOFMS results have been compared with wavelength dispersive x-ray fluorescence analyses for the elemental composition determination and with x-ray photoelectron spectroscopy and time of flight secondary ion mass spectrometry (TOF-SIMS) for elemental distributions. Relative sensitivity factors have been developed for the comparison of PP-TOFMS with TOF-SIMS results. The PP-TOFMS was able to determine the relative composition of In and Al in the thin films with an accuracy of 10 rel. % without calibration. Depth profiles acquired from the PP-TOFMS technique were obtained within a few minutes and exhibited very similar In, Al, and Ga distributions to TOF-SIMS measurements, and thus PP-TOFMS has been shown to be a valuable addition to TOF-SIMS analysis for a fast process dev...