Dual catalysis: combining photoredox and Lewis base catalysis for direct Mannich reactions.

Dual catalysis: combining photoredox and Lewis base catalysis for direct Mannich reactions.
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DOI:
10.1039/c0cc04539j
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发表时间:
2011-02
影响因子:
4.9
通讯作者:
M. Rueping;C. Vila;Rene M. Koenigs;Konstantin Poscharny;David C. Fabry
M. Rueping;C. Vila;Rene M. Koenigs;Konstantin Poscharny;David C. Fabry
中科院分区:
化学2区
文献类型:
--
作者:
M. Rueping;C. Vila;Rene M. Koenigs;Konstantin Poscharny;David C. Fabry

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开发了一种光氧化还原和刘易斯碱催化相结合的双催化体系。通过选择合适的光源和催化剂,可以最佳地调节光氧化还原循环以匹配碱催化的反应循环,从而在温和的反应条件下提供相应的产物。
A dual catalytic system combining photoredox and Lewis base catalysis has been developed. By the appropriate choice of light source and catalyst, the photoredox cycle can be optimally modulated to match the base catalyzed reaction cycle to provide the corresponding products under mild reaction conditions.