Organometallic sesquialkoxides of aluminium, gallium and indium.
Organometallic sesquialkoxides of aluminium, gallium and indium.
复制标题
铝、镓和铟的有机金属倍半醇盐。
DOI：
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发表时间：
2003
影响因子：
46.2
通讯作者：
B. Neumüller
中科院分区：
文献类型：
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作者：
B. Neumüller
铝的有机金属倍半卤化物是技术过程中重要的中间体。然而，这些化合物及其具有镓或铟中心的同系物迄今为止尚未得到结构表征。另一方面，有机金属倍半醇盐已被分离。将讨论主要的合成路线和相应产物的结构。此外，将显示以倍半醇盐作为离析物的笼构反应。讨论将主要集中在合成、光谱结果和结构比较上。由于与众所周知的土金属醇盐的结构连接，其结构图案尤其值得关注。
Organometallic sesquihalides of aluminium are important intermediates in technical processes. However, those compounds and their homologues with gallium or indium centers have not been structurally characterized so far. On the other hand organometallic sesquialkoxides have been isolated. The major synthetic routes and the structures of the corresponding products will be discussed. Furthermore, cage-contructiveness reactions having sesquialkoxides as educts will be shown. Discussion will focus primarily on the syntheses, the spectroscopic findings and a structural comparison. Especially the structural motifs deserve attention because of the structural connection to the well-known earth metal alkoxides.