Mechanical Alloying of Metal-Organic Frameworks
Mechanical Alloying of Metal-Organic Frameworks
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DOI：
10.1002/anie.201612587
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发表时间：
2017-02-20
影响因子：
16.6
通讯作者：
Kitagawa, Susumu
中科院分区：
文献类型：
--
作者：
Panda, Tamas;Horike, Satoshi;Kitagawa, Susumu
The solvent-free mechanical milling process for two distinct metal-organic framework (MOF) crystals induced the formation of a solid solution, which is not feasible by conventional solution-based syntheses. X-ray and STEM-EDX studies revealed that performing mechanical milling under an Ar atmosphere promotes the high diffusivity of each metal ion in an amorphous solid matrix; the amorphous state turns into the porous crystalline structure by vapor exposure treatment to form a new phase of a MOF solid solution.
