Quantitative dynamic interconversion between AgI-mediated capsule and cage complexes accompanying guest encapsulation/release
Quantitative dynamic interconversion between AgI-mediated capsule and cage complexes accompanying guest encapsulation/release
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DOI：
10.1002/anie.200462394
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发表时间：
2005-01-01
影响因子：
16.6
通讯作者：
Shionoya, M
中科院分区：
文献类型：
--
作者：
Hiraoka, S;Harano, K;Shionoya, M
(给出的化学方程式)AgI和盘状三齿配体分别以1：1和1.5：1的浓度比形成容纳主体：囊状和笼状配合物，它们之间的相互转化是可逆的。胶囊复合体可以将金刚烷等中性小分子包裹在内部空间，但采用笼状结构时会释放客体。
(Chemical Equation Presented) An accommodating host: Capsule-and cage-shaped complexes are formed from Ag I and disk-shaped trismonodentate ligands in 1: 1 and 1.5: 1 concentration ratios, respectively; their interconversion is reversible. The capsule complex can entrap a small neutral molecule such as adamantane in the inner space, but the guest is released when the cage structure is adopted.