Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals

Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals
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DOI:
10.1039/c3dt50679g
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发表时间:
2013-01-01
影响因子:
4
通讯作者:
Furukawa, Shuhei
Furukawa, Shuhei
中科院分区:
化学2区
文献类型:
--
作者:
Hirai, Kenji;Chen, Kebi;Furukawa, Shuhei

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杂化多孔配位聚合物(PCPs)是通过外延生长或配体置换合成的。而在核晶体上的外延生长导致三明治型PCP,在核晶体的表面附近的配体置换的结果在核-壳型PCP。
Hybridized porous coordination polymers (PCPs) are synthesized through epitaxial growth or ligand replacement. Whereas epitaxial growth on the core crystal leads to a sandwich type PCP, ligand replacement near the surface of core crystal results in a core-shell type PCP.