An efficient one-pot synthesis of unsymmetrical ethers:: A directly reductive deoxygenation of esters using an InBr3/Et3SiH catalytic system

An efficient one-pot synthesis of unsymmetrical ethers:: A directly reductive deoxygenation of esters using an InBr3/Et3SiH catalytic system
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DOI:
10.1021/jo070814z
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发表时间:
2007-07-20
影响因子:
3.6
通讯作者:
Konakahara, Takeo
Konakahara, Takeo
中科院分区:
化学2区
文献类型:
--
作者:
Sakai, Norio;Moriya, Toshimitsu;Konakahara, Takeo

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这项研究描述了一种新的一锅法,在催化量的InBr3存在下,Et3SiH将酯的羰基直接还原为相应的醚。
This study describes a novel one-pot procedure for a directly reductive conversion of the carbonyl function of esters to the corresponding ethers by Et3SiH in the presence of a catalytic amount of InBr3.