Synthesis and Derivatization of Hetera-Buckybowls
Synthesis and Derivatization of Hetera-Buckybowls
复制标题
Hetera-Buckybowls 的合成与衍生化
DOI：
10.1039/d0ob01931c
复制
发表时间：
2021
影响因子：
3.2
通讯作者：
Shao Xiangfeng
中科院分区：
文献类型：
--
作者：
Wang Wenbo;Shao Xiangfeng
巴基碗表面凹凸有致，π电子云分布明显，与平面芳香多环化合物相比，具有独特的结构和电子特征。杂原子掺入杂基碗的π-骨架是一种调整其固有性能的有效方法，因为杂原子的性质对杂基碗的结构和电子特性起着关键的作用。杂巴基碗的设计、合成和衍生化为获得迷人的有机实体开辟了一条道路，不仅具有重要的基础意义，而且在光电子学中也有很好的应用。本文综述了杂巴基碗化学的研究进展，特别是杂巴基碗支架的合成策略。
Buckybowls have concave and convex surfaces with distinct π-electron cloud distribution, and consequently they show unique structural and electronic features as compared to planar aromatic polycycles. Doping the π-framework of buckybowls with heteroatoms is an efficient scheme to tailor inherent properties, because the nature of heteroatoms plays a pivotal role in the structural and electronic characteristics of the resulting hetera-buckybowls. The design, synthesis, and derivatization of hetera-buckybowls open an avenue for obtaining fascinating organic entities not only of fundamental importance but also of promising applications in optoelectronics. In this review, we summarize the advances in hetera-buckybowl chemistry, particularly the synthetic strategies toward these scaffolds.