Formation of Nb2O5 nanotube Arrays through phase transformation

Formation of Nb2O5 nanotube Arrays through phase transformation
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DOI:
10.1002/adma.200701752
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发表时间:
2008-03-05
期刊:
影响因子:
29.4
通讯作者:
Xue, Dongfeng
Xue, Dongfeng
中科院分区:
材料科学1区
文献类型:
--
作者:
Yan, Chenglin;Xue, Dongfeng

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报道了从伪六边形Nb 2 O 5纳米棒阵列成功合成单斜Nb 2 O 5纳米管阵列(见图);该合成基于伴随空隙形成的相变,其中空隙可以在相变期间有趣地产生。实现纳米管生长的一个关键参数是准六方晶系和非单斜晶系Nb 2 O 5纳米结构之间的能量差,这决定了相变。
The successful synthesis of monoclinic Nb2O5 nanotube arrays (see figure) from pseudo-hexagonal Nb2O5 nanorod arrays is reported; the synthesis is based on phase transformation accompanied by void formation, where voids can be intriguingly generated during phase transformation. A key parameter for achieving nanotube growth is the energy difference between the pseudohexagonal and inonoclinic Nb2O5 nanostructures, which determines the phase transformation.