Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry.
Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry.
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DOI：
10.1002/anie.201006938
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发表时间：
2011-04
影响因子：
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通讯作者：
Elizabeth F. Wilson;H. Miras;Mali H. Rosnes;L. Cronin
中科院分区：
文献类型：
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作者：
Elizabeth F. Wilson;H. Miras;Mali H. Rosnes;L. Cronin
电喷雾离子化质谱（ESI-MS）允许实时监测有机-无机聚氧乙烯酸盐混合体系的“溶液中”形成（见图）。这提供了对与三（羟甲基）氨基甲烷配体配位的锰-安德森簇的形成所涉及的重排的洞察，通过在Mn（CH 3CO 2）3存在下[α-Mo 8 O26]4−簇的重排。
Electrospray ionization mass spectrometry (ESI-MS) allows monitoring of the real-time, “in-solution” formation of an organic–inorganic polyoxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese-Anderson cluster coordinated with tris(hydroxymethyl)aminomethane ligands, through the rearrangement of the [α-Mo8O26]4− cluster in the presence of Mn(CH3CO2)3.