Fac-mer Isomerization of Mo(CO)3(Phosphite)3 Caused by Interaction Between Phosphite Oxygen and Silane Silicon
Fac-mer Isomerization of Mo(CO)3(Phosphite)3 Caused by Interaction Between Phosphite Oxygen and Silane Silicon
复制标题
亚磷酸氧与硅烷硅相互作用引起Mo(CO)3(亚磷酸酯)3的Fac-mer异构化
DOI：
10.1080/10426507.2010.520290
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发表时间：
2011
期刊：
影响因子：
--
通讯作者：
H. Nakazawa
中科院分区：
文献类型：
--
作者：
Kozo Fukumoto;H. Nakazawa
发现Mo（CO）_3 {P（OMe）_3}_3在Me_3EX（E = Si，Ge，Sn; X = Cl，Br，I）的催化下发生异构化反应，并达到平衡。催化活性取决于E（Si > Ge > Sn）和X（Cl < Br < I），而最终平衡位置与E和X的种类无关。对异构化的可能机理进行了讨论。
Abastract The isomerization of Mo(CO)3{P(OMe)3}3 from fac to mer forms was found to be catalyzed by Me3EX (E = Si, Ge, Sn; X = Cl, Br, I), and reached the equilibrium. The catalytic activity depends on E (Si > Ge > Sn) and on X (Cl < Br < I), whereas the final equilibrium position was independent of the kinds of E and X. A plausible mechanism for the isomerization was discussed.