Group V Endohedral Fullerenes: N@C60, N@C70, and P@C60
Group V Endohedral Fullerenes: N@C60, N@C70, and P@C60
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V 族内嵌富勒烯：N@C60、N@C70 和 P@C60
DOI：
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发表时间：
2002
期刊：
影响因子：
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通讯作者：
A. Hirsch
中科院分区：
文献类型：
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作者：
B. Pietzak;A. Weidinger;K. Dinse;A. Hirsch
本文介绍了N@C60、P@C60和N@C70的合成及其性质。这些体系的显著特征是封闭的氮和磷原子保持其原子基态构型，并定域在富勒烯的中心。原子几乎自由地悬浮在这些分子笼子中，表现出类似于电磁陷阱中的离子的性质，即尖锐的光谱跃迁和长寿命。由于富勒烯外壳易于操纵，因此可以实现各种不同的物理或化学修饰。
In this article, the production and the properties of endohedral fullerenes N@C60, P@C60 and N@C70 are described. The distinct feature of these systems is that the enclosed nitrogen and phosphorous atoms keep their atomic ground state configuration and are localized in the center of the fullerenes. The atoms are almost freely suspended in these molecular cages and exhibit properties resembling those of ions in electromagnetic traps, i.e. sharp spectroscopic transitions and long life times. Since the fullerene shell can be easily manipulated, a large variety of different physical or chemical modifications can be realized.