β-Oxochlorin cobalt( ii ) complexes catalyze the electrochemical reduction of CO 2
β-Oxochlorin cobalt( ii ) complexes catalyze the electrochemical reduction of CO 2
复制标题
β-氧二氢钴( ii )配合物催化CO 2 的电化学还原
DOI：
10.1039/d1cc00573a
复制
发表时间：
2021
影响因子：
4.9
通讯作者：
Angeles-Boza, Alfredo M.
中科院分区：
文献类型：
--
作者：
Nganga, John;Chaudhri, Nivedita;Brückner, Christian;Angeles-Boza, Alfredo M.
受血红素d1大环结构的启发，对一系列合成的单-、二-和三-β-氧代取代的卟啉类钴（II）配合物作为电催化CO2还原剂进行了评价，确定了在产生多电子还原产物（包括CH 4）方面具有异常高效率的配合物。
Inspired by the architecture of the macrocycle of heme d1, a series of synthetic mono-, di- and tri-β-oxo-substituted porphyrinoid cobalt(II) complexes were evaluated as electrocatalytic CO2 reducers, identifying complexes of unusually high efficiencies in generating multi-electron reduction products, including CH4.