A Micellar Catalysis Strategy for Amidation of Alkynyl Bromides: Synthesis of Ynamides in Water
A Micellar Catalysis Strategy for Amidation of Alkynyl Bromides: Synthesis of Ynamides in Water
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炔基溴酰胺化的胶束催化策略：水中合成酰胺
DOI：
10.1002/ejoc.201801601
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发表时间：
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通讯作者：
Shenlin Huang
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作者：
Yunqin Yang;Xiangtai Meng;Baolong Zhu;Ying Jia;Xiaoji Cao;Shenlin Huang
Copper‐catalyzed amidation of alkynyl bromides can be carried out in water for the first time, which is made possible by a micellar catalysis strategy using rosin‐based surfactant APGS‐550‐M. The surfactant can be easily prepared from natural abundant biomass, resin acids. Studies as to substrate scope and reaction aqueous medium recycling showcase the ease and sustainability of this technology.
