Solubility of stearic acid in various organic solvents and its prediction using non-ideal solution models

Solubility of stearic acid in various organic solvents and its prediction using non-ideal solution models
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DOI:
10.2306/sclenceasia1513-1874.2007.33.469
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发表时间:
2007-05
期刊:
影响因子:
1.2
通讯作者:
R. Heryanto;M. Hasan;E. C. Abdullah;A. C. Kumoro
R. Heryanto;M. Hasan;E. C. Abdullah;A. C. Kumoro
中科院分区:
综合性期刊4区
文献类型:
--
作者:
R. Heryanto;M. Hasan;E. C. Abdullah;A. C. Kumoro

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用重量法测定了硬脂酸在乙醇、甲醇、乙酸乙酯和丙酮中的溶解度,温度范围为301 ~ 313k。硬脂酸在乙酸乙酯中的溶解度最高,其次是乙醇、丙酮和甲醇。所有实验数据均采用非理想解模型,即修正的Apelblat方程和Buchowski方程进行关联。计算结果与实验数据吻合较好。
The solubility of stearic acid in ethanol, methanol, ethyl acetate, and acetone has been measured gravimetrically at various temperatures ranging from 301 to 313 K at atmospheric condition. The solubility of stearic acid in ethyl acetate was found to be the highest, followed by ethanol, acetone and methanol. All experimental data were correlated using non-ideal solution models, namely, the modified Apelblat and the Buchowski equations. The calculated results agreed well with the experimental data.