Synthesis of K2SiF6 : Mn4 + Red Phosphor from Silica Glasses by Wet Chemical Etching in HF / KMnO4 Solution
Synthesis of K2SiF6 : Mn4 + Red Phosphor from Silica Glasses by Wet Chemical Etching in HF / KMnO4 Solution
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DOI：
10.1149/1.3148270
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发表时间：
2009-08
影响因子：
--
通讯作者：
Toru Takahashi;S. Adachi
中科院分区：
文献类型：
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作者：
Toru Takahashi;S. Adachi
介绍了用湿法化学腐蚀法合成K2 SiF 6：Mn 4+红色荧光粉的方法.所用的起始材料是二氧化硅玻璃（熔融石英、硼硅酸盐和钠钙玻璃）。室温下，将石英玻璃插入HF/KMnO 4溶液中，合成了波长为630 nm的红色荧光粉。光致发光和光致发光激发光谱表明，玻璃合成的荧光粉和单晶硅片之间的光谱特征没有明显的差异。
We demonstrate a method of synthesizing K 2 SiF 6 :Mn 4+ red phosphor by wet chemical etching. The starting materials used are silica glasses (fused quartz, borosilicate, and soda-lime glasses). The red phosphor emitting at λ ∼ 630 nm is synthesized by inserting the silica glasses into a HF/KMnO 4 solution at room temperature. The photoluminescence and photoluminescence excitation spectroscopy show no clear difference in the spectral feature between the glass-synthesized phosphor and the single-crystalline Si wafers.