ScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core.
ScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core.
复制标题
ScorpoPhos：一种新型膦氮配体，含有三（吡唑基）硼酸酯配体核心。
作者：
S. Kealey;N. Long;P. Miller;Andrew J. P. White;A. Gee
本文报道了一种新的三吡唑硼酸酯配体，它的吡唑环3位上带有膦给体基团，并研究了这种三氮磷配体与K ~+、Tl ~+和Cu ~+配位时的半不稳定行为。
A new tris(pyrazolyl)borate ligand bearing phosphine donor groups appended to the 3-position of the pyrazolyl rings is reported, and the hemilabile behaviour of this tris-N,P ligand in coordination with K+, Tl+ and Cu+ ions is investigated.