NHC–Pd(II) complex–Cu(I) co‐catalyzed homocoupling reaction of terminal alkynes
NHC–Pd(II) complex–Cu(I) co‐catalyzed homocoupling reaction of terminal alkynes
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DOI：
10.1002/aoc.1139
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发表时间：
2006-11
影响因子：
3.9
通讯作者：
M. Shi;Heng-xin Qian
中科院分区：
文献类型：
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作者：
M. Shi;Heng-xin Qian
由反式环己烷-1，2-二胺合成的两个NHC-Pd(II)配合物在NHC-Pd(II)配合物/铜共催化的末端炔烃均偶联反应中，在温和的条件下以较高的产率得到了相应的对称的1，4-二取代1，3-二炔。版权所有©2006 John Wiley&Sons，Ltd.
Two NHC–Pd(II) complexes synthesized from trans-cyclohexane-1,2-diamine were fairly effective in the NHC–Pd(II) complex/Cu co-catalyzed terminal alkyne homocoupling reaction to give the corresponding symmetrical 1,4-disubstituted 1,3-diynes in good yields under mild conditions. Copyright © 2006 John Wiley & Sons, Ltd.