Formation of poly(vinyl alcohol)‐titanium lactate hybrid nanofibers and properties of TiO2 nanofibers obtained by calcination of the hybrids

Formation of poly(vinyl alcohol)‐titanium lactate hybrid nanofibers and properties of TiO2 nanofibers obtained by calcination of the hybrids
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DOI:
10.1002/app.25769
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发表时间:
2007-04
影响因子:
3
通讯作者:
K. Nakane;K. Yasuda;T. Ogihara;N. Ogata;Shinji Yamaguchi
K. Nakane;K. Yasuda;T. Ogihara;N. Ogata;Shinji Yamaguchi
中科院分区:
化学3区
文献类型:
--
作者:
K. Nakane;K. Yasuda;T. Ogihara;N. Ogata;Shinji Yamaguchi

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新型有机-无机杂化纳米纤维,即聚乙烯醇(PVA)-乳酸钛(TL)杂化纳米纤维,采用水作为溶剂通过静电纺丝形成。通过在空气中煅烧混合纳米纤维获得锐钛矿型二氧化钛纳米纤维。 PVA-TL杂化纳米纤维的纤维直径为200-350 nm,TiO2纳米纤维的纤维直径为PVA-TL杂化纳米纤维的70-80%。 500℃煅烧5h的TiO2纳米纤维的比表面积和平均孔径分别为21.0m2/g和7.4nm。还研究了使用 TiO2 纳米纤维光催化分解亚甲基蓝。 © 2007 Wiley periodicals, Inc. J Appl Polym Sci 104: 1232–1235, 2007
New organic-inorganic hybrid nanofibers, poly(vinyl alcohol) (PVA)-titanium lactate (TL) hybrid nanofibers, were formed by electrospinning employing water as a solvent. Anatase-type TiO2 nanofibers were obtained by calcination of the hybrid nanofibers in air. The fiber diameters of the PVA-TL hybrid nanofibers was 200–350 nm, and the fiber diameter of the TiO2 nanofibers was 70–80% of that of the PVA-TL hybrid nanofibers. The specific surface area and average pore diameter of the TiO2 nanofiber calcined at 500°C for 5 h were 21.0 m2/g and 7.4 nm, respectively. The photocatalytic decomposition of methylene blue using the TiO2 nanofibers was also investigated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1232–1235, 2007