A one-dimensional homochiral Mo(IV)-Cu(II) coordination polymer: spontaneous resolution and photoresponsive properties
A one-dimensional homochiral Mo(IV)-Cu(II) coordination polymer: spontaneous resolution and photoresponsive properties
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DOI：
10.1039/c0ce00178c
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发表时间：
2010-11
期刊：
影响因子：
3.1
通讯作者：
Wen Zhang;Haoling Sun;O. Sato
中科院分区：
文献类型：
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作者：
Wen Zhang;Haoling Sun;O. Sato
A one-dimensional homochiral MoIVCuII compound, [Cu(tren)][Cu(33)][Mo(CN)8]·4H2O (1, tren = tris(2-aminoethyl)amine, 33 = bis(3-aminopropyl)amine), was synthesized and characterized. Compound 1 experiences spontaneous resolution from achiral components and crystallized in a chiral space group P21. It exhibits photomagnetism via photoinduced metal-to-metal charge transfer, making it a novel example of multifunctional molecule-based materials.
