Apatite Formation on Calcium Phosphate Invert Glasses in Simulated Body Fluid

Apatite Formation on Calcium Phosphate Invert Glasses in Simulated Body Fluid
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DOI:
10.1111/j.1151-2916.2001.tb00676.x
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发表时间:
2004-12
影响因子:
3.9
通讯作者:
T. Kasuga;Y. Hosoi;M. Nogami;M. Niinomi
T. Kasuga;Y. Hosoi;M. Nogami;M. Niinomi
中科院分区:
材料科学2区
文献类型:
--
作者:
T. Kasuga;Y. Hosoi;M. Nogami;M. Niinomi

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通过添加少量 TiO2 制备了含有 P2O72− 和 PO43− 离子的磷酸钙反相玻璃。在 37°C 温度下的模拟体液 (SBF) 中检查磷酸盐倒置玻璃表面骨状磷酸钙磷灰石的形成。浸泡20 d后,6CaO·3P2O5·TiO2反相玻璃上沉积有叶状磷灰石颗粒(基于摩尔比)。与偏磷酸盐玻璃相比,该玻璃对 SBF 具有更高的化学耐久性; P离子没有从6CaO·3P2O5·TiO2玻璃中过量溶解,因此磷灰石的形成没有受到抑制。
Calcium phosphate invert glasses, which contain P2O72− and PO43− ions, have been prepared via the addition of a small amount of TiO2. The formation of bonelike calcium phosphate apatite on the surface of the phosphate invert glasses was examined in simulated body fluid (SBF) at a temperature of 37°C. Soaking for 20 d resulted in the deposition of leaflike apatite particles on 6CaO·3P2O5·TiO2 invert glass (based on molar ratio). The glass had much-greater chemical durability against SBF, in comparison with a metaphosphate glass; P ions were not dissolved excessively from the 6CaO·3P2O5·TiO2 glass, so the apatite formation was not suppressed.