Studies of the reactions of SiO and silver atoms in hydrocarbon matrices at 77 K

Studies of the reactions of SiO and silver atoms in hydrocarbon matrices at 77 K
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77 K 烃基体中 SiO 与银原子反应的研究

DOI:
10.1039/c39900000581
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发表时间:
1990
期刊:
Journal of The Chemical Society, Chemical Communications
影响因子:
--
通讯作者:
P. Timms
P. Timms
中科院分区:
--
文献类型:
--
作者:
J. H. B. Chenier;J. Howard;H. Joly;B. Mile;P. Timms

文献摘要

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电子顺磁共振(EPR)研究表明,在77K下,银原子与金刚烷基质中的SiO反应生成了Ag(SiO)、Ag(SiO)、Ag(Si2O_2)、Ag(SiO_3)和Ag(SiON),并讨论了这些物种中的成键。
Electron paramagnetic resonance (EPR) spectroscopic studies indicate that reaction of Ag atoms with SiO in an adamantane matrix at 77 K yields Ag(SiO), Ag(SiO), Ag(Si2O2), Ag(Si3O3), and Ag(SinOn); the bonding in these species is discussed.