Novel domino elimination-rearrangement-addition reaction of N-alkoxy(arylmethyl)amines to N-alkyl arylamines
Novel domino elimination-rearrangement-addition reaction of N-alkoxy(arylmethyl)amines to N-alkyl arylamines
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DOI：
10.1055/s-2006-949642
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发表时间：
2006-09-01
期刊：
影响因子：
2
通讯作者：
Naito, Takeaki
中科院分区：
文献类型：
--
作者：
Miyata, Okiko;Ishikawa, Tatsuya;Naito, Takeaki
首次开发了一种新的N-烷氧基（芳甲基）胺生成N-烷基芳胺的多米诺反应，该反应由三类反应组成：醇的消除、芳基的重排以及有机锂或镁试剂的加成。
A new domino reaction of N-alkoxy(arylmethyl)amines to N-alkyl arylamines, consisting of three types of reactions: elimination of alcohol, rearrangement of the aryl group, and addition of an organolithium or a magnesium reagent, has been developed for the first time.