(Hexamethylbenzene)Ru catalysts for the Aldehyde-Water Shift reaction

(Hexamethylbenzene)Ru catalysts for the Aldehyde-Water Shift reaction
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DOI：
10.1039/d0gc03809a
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发表时间：
2021-03
期刊：
Green Chemistry
影响因子：
9.8
通讯作者：
Alexander S. Phearman;Je Moore;D. Bhagwandin;J. Goldberg;D. Heinekey;K. I. Goldberg
Alexander S. Phearman;Je Moore;D. Bhagwandin;J. Goldberg;D. Heinekey;K. I. Goldberg
中科院分区：
化学1区
文献类型：
--
作者：
Alexander S. Phearman;Je Moore;D. Bhagwandin;J. Goldberg;D. Heinekey;K. I. Goldberg

文献摘要

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醛-水变换（AWS）反应使用H2O作为良性氧化剂将醛转化为羧酸，产生H2，一种有价值的试剂和燃料，作为其唯一的副产物。（六甲基苯）RuII配合物与以前报道的催化剂相比，具有更高的歧化活性和选择性（高达95%）。
The Aldehyde-Water Shift (AWS) reaction uses H2O as a benign oxidant to convert aldehydes to carboxylic acids, producing H2, a valuable reagent and fuel, as its sole byproduct. (Hexamethylbenzene)RuII complexes are demonstrated to have higher activity and selectivity (up to 95%) for AWS over disproportionation than previously reported catalysts.