Photochemical C-H oxygenation of side-chain methyl groups in polypropylene with chlorine dioxide
Photochemical C-H oxygenation of side-chain methyl groups in polypropylene with chlorine dioxide
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DOI：
10.1039/c9cc01037h
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发表时间：
2019-04-25
影响因子：
4.9
通讯作者：
Inoue, Tsuyoshi
中科院分区：
文献类型：
--
作者：
Ohkubo, Kei;Asahara, Haruyasu;Inoue, Tsuyoshi
二氧化氯自由基（ClO 2）被发现作为一个有效的氧化剂的有氧C-H氧化的侧链甲基在聚丙烯在光辐射和环境条件下（298 K和1大气压）。含氧侧链甲基选择性转化为羧酸和羟基。
The chlorine dioxide radical (ClO2) was found to act as an efficient oxidizing agent for the aerobic C-H oxygenation of the side-chain methyl groups in polypropylene under photoirradiation and ambient conditions (298 K and 1 atm). The oxygenated side-chain methyl groups were selectively converted to carboxylic acid and hydroxy groups.