Synthesis of hydrophosphorylated fullerene under neutral conditions.
Synthesis of hydrophosphorylated fullerene under neutral conditions.
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DOI：
10.1021/ol0522586
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发表时间：
2005-11
期刊：
影响因子：
5.2
通讯作者：
H. Isobe;Ai-Jan Chen;N. Solin;E. Nakamura
中科院分区：
文献类型：
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作者：
H. Isobe;Ai-Jan Chen;N. Solin;E. Nakamura
[化学反应：见正文]。在DMSO/C6 H5 Cl中，各种磷化合物如仲膦、氧化膦、次膦酸盐和膦酸盐在没有外来试剂的情况下与[60]富勒烯加成，以中等至高产率产生氢磷酸化富勒烯衍生物。
[chemical reaction: see text]. A variety of phosphorous compounds such as secondary phosphines, phosphine oxides, phosphinates, and phosphonates undergo addition to [60]fullerene in DMSO/C6H5Cl without extraneous reagents to produce hydrophosphorylated fullerene derivatives in moderate to high yield.