Green Synthesis of Reticular Materials
Green Synthesis of Reticular Materials
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DOI：
10.1002/adfm.202304660
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发表时间：
2023-09
影响因子：
19
通讯作者：
Aamod V. Desai;E. Lizundia;Andrea Laybourn;Daniel N. Rainer;A. R. Armstrong;Russell E. Morris;Stefan Wuttke;Romy Ettlinger
中科院分区：
文献类型：
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作者：
Aamod V. Desai;E. Lizundia;Andrea Laybourn;Daniel N. Rainer;A. R. Armstrong;Russell E. Morris;Stefan Wuttke;Romy Ettlinger
为了帮助确保地球上的子孙后代拥有繁荣的未来，学术界和工业界需要改变他们规划和合成新材料的方式，使它们在环境上更加可持续。特别是网状材料领域，即金属有机骨架、沸石咪唑酯骨架和共价有机骨架，具有超越其他材料并彻底改变各个应用领域的巨大潜力。本综述重点介绍了绿色化学原则范围内的起始材料、溶剂和合成方法选择的几个关键方面，并通过提供再利用、再生或回收等相关策略纳入循环经济视角，以最大限度地提高地球可用资源的价值。此外，它将揭示所选网状材料的生命周期评估结果，并考虑绿色化学原理、生命周期评估指标和循环模式所施加的约束将如何塑造未来合理的可持续设计和网状材料的发现。
To help ensure a prosperous future on Earth for coming generations, academia and industry need to transform the way they plan and carry out the synthesis of novel materials to make them more environmentally sustainable. In particular, the field of reticular materials, i.e., metal‐organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks, has great potential to outperform other materials and revolutionize various fields of applications. This review highlights several key aspects from the choice of their starting materials, solvents and synthetic methodologies that fall under the umbrella of the Green Chemistry principles, and incorporates a Circular Economy perspective by providing relevant strategies such as reuse, regeneration, or recycling to maximize the value of the Earth's available resources. Moreover, it will shed light on the life cycle assessment results of selected reticular materials and consider how constraints imposed by Green Chemistry principles, life cycle assessment metrics, and circular patterns will shape the future rational sustainable design and discovery of reticular materials.